Kamerer: You are absolutely right about prolonged repeated exposure to many of the chemicals we use in ordinary life. However,
Probably not the place for a prolonged discussion of toxic affects of acetone or other chemicals. If you have data supporting your contentions you can send them to
[email protected].
You are seriously misinformed on the chemistry and dangers of these chemicals. First, while your observations of injury and illness from prolonged and uncontrolled exposure to acetone in the third world could be valid, I'd have to ask what other chemicals were they concurrently exposed to? The only information on acetone toxicity from "massive" animal trials is the potential for liver damage and cellular necrosis. This comes from feeding animals with concentrations up to 50,000 ppm (5%) acetone for long periods. Note also, human metabolic processes produce acetone in small amounts. Check also ATSDR for the effects of exposure to acetone. Acetone is used for lots of things, including nail polish remover.
Ketones do not form hydroxyl anions (or OH radicals for that matter) without some serious chemistry steps. Your chemistry is dead wrong. When they evaporate, the whole molecule, not some reactive part evaporates. Also, you cannot evaporate just an anion (OH-). You have to take the cation with it as a neutral chemical compound. Your example of household bleach (sodium hypochlorite) is correct in that it generates hydroxyl anions. These are not the active, potentially dangerous component. The dangerous component is the hypochlorite anion. Which is the bleaching agent. Hypochlorite is corrosive and, if acid is added, can generate chlorine (Cl2). Note: hypochorite is commonly used for disinfecting swimming pools and can be used for disinfecting drinking water, but chlorine gas is generally used for disinfecting large volumes of drinking water. Chlorine gas reacts with water to form hypochorous acid, the bleach and disinfectant. Try household ammonia for creating hydroxyl anion: from the reaction of ammonia gas with water to form ammonium hydroxide. Both laundry bleach and household ammonia are more damaging on contact than either acetone or MEK.
If your "progressive" chemical education taught you this, then they did you a serious disservice. The chemistry you are putting out would get an F in any freshman course I taught for being just plain wrong. No political slant involved.