I knew one person who measured case capacity the correct way that eliminates the shape and dimension variables. He cut the top off a full length sizing die such that when in his press full into it, the case neck stuck out the top about 1/16". He used new cases without powder residue that might absorb water. Their empty weights were recorded. All cases pushed full into that die had the same outside shape and dimensions. The only variable was case wall thickness and their powder space volume then varied by those alone.
Cases were filled with water that was mixed with a wetting agent. Cases were pulled carefully out of the die then slid out of the shell holder then weighed. Each case weight was subtracted and the result was case capacity in water.
Weights of 308 and 7.62 cases I've measured range from 149 grains (Western Ctg Co, 1958 match) to 185 grains (CBC, unknown year). Here are others:
Winchester at 157.13, Winchester nickel plated at 159.82, Hornady Match at 166.29, PPU at 166.94, Federal 308 WIN at 176.90, Lake City NM 68 at 177.55, Lake City Match 91 at 177.98, Lake City Match 77 at 178.45, GFL at 178.89, WCC at 179.48, PMC at 179.50 and CBC Nato 12 at 183.09.