Lead mixing--by weight or volume? And PREVENTING some mixing?

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Deus Machina

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When mixing lead, if you want, say 3% tin, do you measure that by weight or volume? I have yet to find anything that says ".97lb lead, .03lb tin." or the like. I'd like to be able to break stuff down to the basest lead and start from scratch.

A good deal of my lead input will be from wheel weights. I can tell to some extent which are lead and which odd ones are zinc, but assuming a few slip through, does one melt faster than the other and can be separated, or will zinc go oil-on-water and be able to get dipped off the top?
 
Cast Bullets Alloy

% is by weight. Link to Zinc http://www.thehighroad.us/showthread.php?t=389772
At 787.2 F zinc melts. Lead melts at 621.5 F.
But when the alloys are mixed , melting temp. changes. It might be possible for a zinc wheel weight to float on top of the alloy if the tempature is raised slowly on the pot. But if the mix has a high contant of antimony, i would think no. :confused: Look up the melting temperature for each metal, keeping in mind that an alloy of 2 different metals will change the melting point higher of lower depending on the content % wise. But antimony and copper may come to the surface also. Bullet Sizes & Weights – How to Vary Them
The bullet diameters and weights presented in this list
are based on the use of Taracorp’s Lawrence Magnum
bullet alloy (2% tin, 6% antimony, 1/4% arsenic,
91.75% lead).
Bullet diameters and weights will vary considerably
depending on the lead casting alloy used. This variation
can be as much as 1/2% on the diameter, and 8% on
the weight among the most commonly used casting
alloys. For example, a .358-158 grain bullet might
show a diameter variation of .002", and a 13 grain difference
in weight.
Of the most commonly used alloys, wheel weights (.5%
tin, 4% antimony, 95% lead) will produce bullets having
the smallest diameter and heaviest weight, with
such bullets running approximately .3% smaller in
diameter and 3% heavier than bullets cast with
Taracorp's metal. Linotype will produce bullets with the
largest diameter and lightest weights. This alloy will
produce bullets approximately 1/10% larger and 3%
lighter than Taracorp. Other alloys of tin and antimony,
with antimony content above 5%, will produce bullets
with diameters and weights falling between those cast
from wheel weights and linotype.
Alloys containing little or no antimony will cast considerably
smaller than wheel weights and in some cases
will produce bullets too small for adequate sizing.
Within the limitations given above, the weight and
diameter of a cast bullet can be adjusted by varying the
alloy’s antimony content.
The size and weight of bullets of a given alloy will also
vary according to casting temperature. Higher temperatures
will result in greater shrinkage as the bullet
cools, thereby producing a slightly smaller and lighter
bullet than one cast of the same alloy at a lower temperature http://www.redding-reloading.com/PDF...ulletchart.pdf While antimony is used to harden the bullet, the mixture of tin is critical, for while antimony mixes with lead in its molten state, it will not remain mixed when it solidifies. If tin were not added, we would have pure antimony crystals surrounded by pure lead. A bullet of this type , while it feels hard , would certainly lead the bore and eliminate all potential for accuracy. In a lead-tin-antimony mixture, the antimony crystals will be present just the same, but they will be imbedded in a lead-tin mixutre. As the bullet cools the tin will form around the antimony-lead keeping your bullets from* leading the bore.
 
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