Don't polish anything.
The Colt DA cylinders don't rotate like S&W and Ruger cylinders do.
The Colt cylinders seem to be sluggish but that's how they work. S&W and Ruger freewheel much easier.
If you think it needs cleaning, remove the cylinder and crane assembly from the frame and pull the crane forward so you can get to the crane shaft.
Clean it off and apply some lube.
DO NOT attempt to disassemble the older Colt cylinder assemblies. That requires two special wrenches, and attempting it without them often damages the assembly.
That means an expensive trip back to Colt for repair, and just hope they have the parts.