With a steel cylinder the tight cylinder gap is a moot point, unless you shoot soft lead bulleted ammunition. Then a lead build-up on the barrel and cylinder face can cause the cylinder to bind. For this reason wide gaps up to .010" were acceptable during past years. Now customers want tighter gaps and the manufacturers have responded.
By it's nature, titanium is softer then steel, and also more elastic. The revolvers I examined clearly had marks on the cylinder face that had been stamped into place, and the barrel was the only thing located close enough to do the stamping. Both were chambered in .357 Magnum, and one of them had been fired with ammunition made by a small manufcturer who specializes in pushing to the highest allowable pressures.
You can open up the cylinder gap a bit without causing problems, but I have no idea how much extra space would be required to eliminate the problem, if indeed more cylinder gap is the answer. The two Taurus revolvers I mentioned were supposedly repaired, but they didn't specify what they did. In both cases the owners then quickly dumped them on the used gun market and I lost any further track of them.