Do not recall how long ago, but someone posted their findings on shooting steel vs brass cased .223 ammo in their AR (they were having problems with steel cases extracing after a few hundred rounds.
Apparently what they discovered was the steel case necks were not expanding to the chamber walls completely, allowing some of the gasses and propellent remains to get back into the chamber sidewall areas, causing it to build up. Brass cases would eject all right, but have indentations on them where they were dragged over the carbon build-up. The steel cases, apparently, were getting stuck on the build-up and not ejecting properly.
I also do not recall which forum it was on, nor the brand of AR they were using.