Appreciate the replies fellas. After researching some more and spending my day off today looking at a couple LGS I'm abandening the notion of getting out to 100yds with a pellet rifle right now. Too rich for my blood.
However I'm still intrigued with the newer "nitro piston" rifles as to whether or not they're any easier to shoot than standard springers. I found a couple of .177 nitro rifles with 4x32 scopes in the $120-150 range today. Would they be better suited for better accuracy at even 50yds? I'd at least like to get better accuracy at 50yds than what I'm getting with my "acclaimed" 800fps .22.
I did however find some ammo today that I will be using as my go to with my .22 for 25-30yds. This stuff was considerably more accurate and consistent than the CM Premier I had been using and have never really liked.
After shooting a golf ball sized group @ 25yds with the above I tried out another type of ammo I picked up today. I'm really confused by the results so maybe some "air experts" here can enlighten me. I realize it's a heavier bullet but I would have thought that would've caused it to drop. Instead you can see the crazy results.
The ammo and the three shots I took before I gave up...