S&W's manuals explain that abrasives, including brushes, should not be utlilized on the titanium cylinders. Apparently titanium, while naturally protected from corrosion by its own oxide layer, is susceptible to being damaged by the blast from firing. S&W applies a protective finish to minimize the blast effects.
On the S&W forum, there are pics of a .357 Magnum titanium-cylindered J-frame with pieces of the titanium cylinder blasted off the surface facing the forcing cone. The revolver was returned to S&W, and the cylinder was replaced.