I have not seen where this has already been mentioned but i saw this add and thought it may help some of you guys that are trying to make percussion caps. It is a company that is making kits to reload .22 long rifle,.22 magnum, and the .17 rimfires. You can buy just the primming compound and says it is enough to load 2000 rounds of rimfire primmers. It is a mix, i think two parts for the explosive and a third that makes it set up hard. I am sure this would work great in a home made caps.
http://22lrreloader.com/
http://22lrreloader.com/