Primer materials
Found this searching the net. Full article can be found here.
http://www.findarticles.com/p/articles/mi_qa3623/is_199903/ai_n8850154
"Priming formulations are mixtures of initiators, fuels, oxidizers and sometimes, sensitizers, frictionators and heat increasers. The initiator is the chemical most often used to describe a primer. The other materials are used to adjust sensitivity, flame output and duration.
Mercury fulminate was the predominant percussion priming chemical for many years. It was first described by the Swedish-German Alchemist Baron Johan Kunkel von Lowenstern (1630-1703). It was suitable for priming, but it was more than 100 years until LePage of France actually tried it in a priming mix. It was then forgotten until Edward Howard rediscovered it around 1799. The Rev. Alexander Forsyth, a Scottish Presbyterian minister, patented mercury fulminate as a percussion initiator in 1807.
Mercury fulminate was later used with the addition of potassium chlorate, antimony sulfide, various fuels, oxidizers, powdered glass and glue to improve storage stability, sensitivity and ignition power. Stronger primers were required as smokeless powder began to replace blackpowder in the late 1880s. By 1910, nearly all straight mercury fulminate primers had been replaced by fulminatechlorate mixes. These mixes were good initiators and were used to load some commercial ammunition into the 1940s. Some military match ammunition was loaded at the Lake City Army Ammunition Plant with these formulations as late as the mid 1960s. Nonetheless, mercury fulminate had several disadvantages. It was costly to make, rapidly decomposed into a non-explosive solid which caused misfires unless stored in a very cool place, and formed an amalgam, or alloy, with brass that would weaken and cause cartridge case failures. ...
Mercury fulminate compositions had been replaced since 1930 by lead styphnate, lead azide, and DDNP (Diazodinitrophenol) mixtures. This occurred first in Germany, then throughout Europe, and finally in the United States.
Initiators start the lead styphnate primer mix going upon firing pin impact. Fuels burn up to generate heat, gases, and incandescent (glowing) particles. Oxidizers provide the oxygen to burn the fuel and other combustibles. Frictionators increase sensitivity of the mix by providing sharp particles for concentrating firing pin energy-most common to rimfire mixes. Binders hold the mix together in the primer. Other materials such as TNT, PETN, DDNP (Diazodinitophenol), powdered aluminum, powdered magnesium and nitrocellulose or guncotton are often employed to increase flame temperature, hot particles or flame duration. "