Bullet Casting Question - Antimony

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Mixed Nuts

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I've seen a recipe for Lyman #2 written as:

90% Lead, 5% Tin, 5% Antimony.

I've been jotting down notes about melting points and salvage possibilities and I'm kinda stumped by something. I've never cast boolits before so bear with me if this is a weird question.

Lead melts at 621 F
Tin melts at 449 F
but...
Antimony melts at 1167.13 F

How can this be? Wouldn't melting Antimony into lead/tin alloy and keeping the whole mix over 1168 F be a problem?

How does the antimony stay melted in the mix at bullet casting temps? What am I missing here?
 
5% antimony doesn't shift the alloy melt point up significantly, since the antimony is in solution with the lead. Antinomy's high melt point does make it difficult to add pure antimony at home, which is why most home casters use pre-alloyed antimony instead.
 
I buy the 30%-70% antimony - lead and have no problem melting it. I can't give a detailed explanation either but the melting point will change depending on the alloy. I miscalculated and used way to much tin once, very low melt point and something like 360 grain bullets from a 405 grain mold.
 
Okay, sounds like the Antimony behaves differently if it's already in a lead alloy. That must be it. There are too many people making bullets at lower temps.

So, I just read that the lead in car batteries is lead already in an alloy with both tin and antimony but that it can't be sourced by the bullet caster because there may be some poisons in the alloy that will become airborne if the battery plates are melted. Bummer.
 
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Antimony will "dissolve" in lead at 630 degrees it just takes time and some stirring. Once alloyed with lead, Antimony (and Tin) lowers the melting temperature of the alloy compared to pure lead. A really good cast bullet alloy is 6% Antimony, 2% tin and 92% lead. If this alloy has even 1/4% Arsenic (chilled shot will provide) it can be water dropped quenched or oven hardened and quenched for extremely hard cast bullets for high velocity/pressure. Depending on how you cool the castings, you can vary the hardness from about BHN12 to as much as 28-32 BHN.
 
Best bet is to get some chilled shot to add in, some wheel weights work just fine as is, or buy from someone like roto-metals pre alloyed lead and mix in with yours. Please do not even consider batteries for lead, it is just not worth it. I don’t pretend to understand the science of it, but I do know how to take certified metals of known composition and mix them to get what I want. Buying Lyman #2 would be the easiest way to go if that is your goal.
 
You can download a free alloy calculator here http://castboolits.gunloads.com/showthread.php?105952-Lead-alloy-calculators it works on Excel or OpenOffice calc. etc. and you can get a general idea of what your mixed alloy will yield. As an example Magnum 7 or 8.5 lead shot has 6% antimony, 1.25% arsenic and about 92% lead if you mix 5 lbs. of that with 15 lbs. of pure lead you will get an as cast bullet BHN of around 10.

Here is what the spreadsheet looks like when open. The area in Yellow is where you punch in you weights, hit enter and the presumed BHN is calculated at the bottom.
d66lopZ.jpg
 

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The antimony doesn't need to melt to go in solution with lead. It simply dissolves.

Think of it as sugar put into water. Sugar melts at a much higher temp than water (ice), but one needn't get the water to the melting point of sugar to get a solution.

The sugar just dissolves in the water. As does antimony in liquid lead.
 
You might read a little more about tin lead and tin lead antimony alloys.

63 tin 37 lead melts at a lower temp than either metal alone. That is called the eutectic alloy.

For lead tin and antimony you have 84/4/12 which is linotype metal.
 
The antimony doesn't need to melt to go in solution with lead. It simply dissolves.

Think of it as sugar put into water. Sugar melts at a much higher temp than water (ice), but one needn't get the water to the melting point of sugar to get a solution.

The sugar just dissolves in the water. As does antimony in liquid lead.

This is a very interesting response and it would tend to explain why antimony and lead bullets can be cast at lowish temperatures.The antimony's not melting at all, but doing something else. I like it.
 
The antimony doesn't need to melt to go in solution with lead. It simply dissolves.

Think of it as sugar put into water. Sugar melts at a much higher temp than water (ice), but one needn't get the water to the melting point of sugar to get a solution.

The sugar just dissolves in the water. As does antimony in liquid lead.
I haven't got into making my own boolits but this seems like the best simple explination.
 
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