The posters here have provided you good information. All of which is detecting the gross indications of gunpowder deterioration. Gunpowder does not get better with age, when the stabilizer in it is depleted, deterioration accelerates. Not only will old gunpowder set itself on fire, the burn rate gets messed up, and it will, and has blown up firearms.
With 45 year old gunpowder, use it up. Don't sit on it, shoot it up. Your powder is well past any expected shelf life date, so shoot it up. Do however load up a small sample first, and shoot the stuff. If you have any "funny" retorts, sticking extraction at "normal" loads, don't shoot anymore. Before I knew of deteriorated gunpowder, I loaded up a couple of kegs of military pulldown IMR 4895. It shot well. But I had the occasional sticking extraction, and once in a while a "funny" retort. More pingy than boomy. In time, that stuff cracked the case necks on 700 loaded LC 308 cases. Do not load a whole bunch of cases and let it sit. When the powder goes bad, it will corrode and ruin the cases.
I have written extensively on the problems of old gunpowder, these are a few:
cause of case head separation
Shooting very old ammo.
Reloads Shelf Life
If you ever see this, just STOP
I believe you expressed the false idea that gunpowder fails benignly, because of the continuing industry misinformation on this topic. You probably read this misinformation by an in print gunwriter, whose articles have three levels of management review. This misinformation was deliberately written to calm and assure the shooting public that very damn old ammunition and gunpowder is perfectly safe, and lasts forever! Nothing you read by influencers, be they old time shills, or internet influencers, will educate you on what not to buy! As Noam Chomsky says
"the purpose of advertising is to create ill informed consumers who make irrational choices"
You gunpowder is old, it is at the end of any reasonable shelf life, sniff it, inspect it, and load a few rounds and see if it is OK. And if it is, shoot it up. It is not getting any younger.