Howdy
Cartridge brass is 70% copper and 30% zinc. This formula was arrived at many years ago for two reasons.
It can be cold worked, which is how cartridge brass is formed.
And it springs back ever so slightly in diameter after firing. Not all the way back to original dimensions, which is why it needs to be resized after shooting.
But it springs back enough that it usually will eject easily.
That will of course depend on the specific gun and its chamber dimensions.
Years ago, when I used to shoot Cowboy Action a lot, I always got a kick out of shooters who would show up at the unloading table and bang the butt of their revolvers on the table to shake the empties out. These were always the guys shooting mouse fart loads that would barely expand at all. I would always ask them if they knew what that doohickey under the barrel was for. (The ejector rod)
By the way, one reason the very early 45-70 loads were so troublesome when fired in a Trapdoor rifle is because the earliest shells were copper, not brass. The copper did not spring back to shape as later cartridge brass does. Plus, the extractor would sometimes rip right through the soft, copper rim, completely jamming the rifle.
The 45-70 round on the left in this photo is an old Benet primed, copper cased 45-70.
The first 45 Colt and 45 Schofield rounds were copper cased too. In the center, a copper cased and Benet primed 45 Colt and 45 Schofield. The Single Action Army has always punched empties out from the inside with a an ejector rod, so sticking in the chamber was probably never a problem. The Schofield revolver used an extractor star not much different than modern revolvers. I do not know if they had problems with extracting copper cased rounds.
Personally, I have always avoided aluminum cased ammo, I would never bother trying to reload it. I have zillions of brass cases for all the cartridges I reload.