The human mind thinks in terms of linear progression. That is, 1, 2, 3, 4, 5, 6, maybe 1, 2, 4, 8, 16, 32, 64, …. However the vast majority of phenomena is exponential. That is something like 1, 2, 4, 16, 256, 65536, 4294967296…
Smokeless propellants have an exponential pressure curve. Small changes cause exponential rates of growth.
So you have to be cautious when developing loads. Start at the low end, I use a chronograph to look at velocities, work your way up.
When you pierce and blow primers, you have exceeded safe limits. When bolt lift gets sticky, you have exceeded safe limits.
Maximum loads are different for each and every rifle. Very tricky.