I have not verified this personally, but I would suppose any of the black powder substitutes would qualify (Pyrodex, etc) or the original, Black Powder itself.
Trail Boss has another characteristic that makes it useful to me. It does not develop high pressures (because of it's volume, it is difficult to load up to high pressures unless you are using a REALLY big case-full). Thus it is the powder I use to teach any novice I mentor.
Lost Sheep
edit: I did not have the preceding answers (posts 3 through 10) on-screen - don't know why), so did not see your purpose. So, my answer is not quite on-point. But I did not delete it because I think it might be useful to others who spot your subject line about "fluffy" or voluminous powders.
Also, my thanks for the mention of other powders that might serve MY purposes. (Walkalong) Red Dot, American Select, Solo 1000, and 700X and N32C "Tin Star" powder by Vihtavuori and (bds) Red Dot and Promo.