LawDog,
If you look at graphs of photopic vs. scotopic vision, you'll see why red light is preferred for dark adaptation. Photopic sensitivity is centered in the mid-550nm wavelength band, while peak spectral sensitivity for scotopic vision (which predominates for the dark-adapted eye) is shifted towards the blue, peaking at about 510nm. This "Purkinje Shift" comes from the differing spectral sensitivities of the rods and cones in the retina.
Blue light will still be activating the rods, which you need to see in the dark, so they won't "dark adapt" as well as they would in complete darkness. But the rods are MUCH less sensitive to light in the red part of the spectrum, so in red light, the rods react almost as if they were in complete darkness, and so they adapt better.
As for shifting from red light to blue to read maps - well, if all you've got is red light to look at color maps, then all you'll see are shades of red, so some markings will wash out. Shifting to dim blue light will restore some of the contrast, making red markings look blacker . . . and as long as the light is dim, it won't affect night vision too much.
On the other hand, visual acuity is affected by color as well. The eye has about 1.5 diopters of chromatic aberration. Normally, visual acuity is given for white light, but for monochromatic yellow and yellow-green light, it actually improves a bit. (Yellow shooting glasses, anyone?) Visual acuity is just slightly lower for red light, but in blue or FAR red light, visual acuity is down by 10%-20%.
Some of this is discussed in the book Modern Optical Engineering by Warren J. Smith.