Short answer, yes you can. But, I would advise staying away from steel case ammo. When practicing, I once had mine "double". A gunsmith who was well aquatinted with 100's told me not to very carefully touch off the shot. Use a firm press instead. They are a great rifle
An older member of the gun club owned one of these Winchester 100’s. He sent it in for the firing pin fix and it still slamfired.
You can look at the diagram here:
http://www.leeroysramblings.com/Gun parts illustrations/Winc100.jpg
And see that it looks as if the firing pin is not positively held back, there is a spring, but it sure looks as if there is the potential for a slamfire due to a sensitive primer.
This might be of interest.
http://www.shootersforum.com/warning-notices-recalls/1662-winchester-model-100-recall.html
This link claims slamfires were due to firing pin breakage. If you had a double, and your gun is not broke, it was either due to a sensitive primer, or you were not firmly holding your rifle and you tripped the trigger on recoil.
http://www.thefirearmsforum.com/threads/tech-tip-winchester-model-100.669/
I don’t know what the firing pin modification was, I suspect it was a lighter firing pin. I would recommend, even if your rifle has the firing pin mod, to use the least sensitive primers on the market, which would be the “mil spec” CCI #34’s or Tula7.62. For factory ammunition I would look for ammunition that is made for the M1a. Federal makes ammunition that is appropriate for the M1a.
http://www.federalpremium.com/products/details/rifle.aspx?id=809 The port pressure on this would be OK for your rifle and I have no doubt that Federal is using their mil spec primers in this ammunition. Federal has made their mil spec small rifle primer available to the public, because of all the AR15 slamfires, but to date, CCI is the only American manufacturer to release their mil spec primers.